Ambergris
Dr. Zhongzhen Zhao
Hong Kong Baptist University
Dr. Li LIANG
Hong Kong Baptist University
Key words: Ambergris, Perfume fixative, Sperm whale, Tai Ping Hui Min He Ji Ju Fang, Egret’s Cough Pill, Cuttlefish
You Cannot Judge Gold by its Glitter
Of the four aromatic materials used in ancient China–ambergris, sandalwood, agarwood, and musk–ambergris ranks first as the most exotic and precious. A news story about ambergris a few years ago demonstrates some of the mystery and intrigue that surrounds this most unusual substance. On June 1, 2014, a Mr. Chen and his family went to the Guanyin Mountain waterfront in Xiamen. He saw a “stone” the size of a fist on the beach. When he picked it up, it was soft and not heavy at all, and it looked a bit like a tree stump soaked in sea water, but it smelled fishy. He put it down and went away, but didn’t go far before he turned back to pick it up again. He smelled it, and threw it on the beach. For the third time, he had already walked a long way, but an idea suddenly popped into his mind, could this be the legendary ambergris? He hurried back. This time, he took the “stinky stone” with him, wondering if he could be so lucky. He took the object to an expert who concluded that it really was ambergris. Chemical analysis determined that the content of ambrein, a major chemical component in ambergris, was as high as 25%. This “stone” was actually top grade ambergris.


Some private ambergris collections of Mr. Chun-hung Lee; Ambergris varies in color from black to almost white
After the news was released, many people began a treasure hunt on the beach, examining every dark stone they could find. However, finding ambergris is as hard as winning the lottery, and none of them succeeded.
The Mystery of Ambergris
Ambergris is an exotic source of fragrance that was first discovered in the Arabian Sea off the coast of Africa. It was usually found washed up on the shore. Like what Mr. Chen found, raw ambergris is a soft, dark grey mass. In ancient times, no one could figure out where it came from.
The name of this substance in Arabic is “Ambar,” In ancient China, the word for fragrant, “xiang” was added, and the name of it was then “Ibaerxiang” or “Ahmadxiang”. “Amber” means “jewel” in Arabic; “gris” is an old and modern European word for “grey”. Thus, ambergris means “amber grey” in English.
Since ambergris came from the sea, the ancients hooked it up with dragons, adding a connotation of dignity to the mystery of ambergris.
Ambergris was recorded in the forty-third volume of the Compendium of Materia Medica. This volume was dedicated to animals with scales (e.g., snakes, lizards, butterflies). It was recorded that ambergris came out of the southwest ocean. Li Shizhen wrote that it might be the saliva of the dragon or that it might come from the belly of a big fish. Which was true? Li Shizhen was not able to draw a conclusion. It was still speculation at that time.
By 1667, throughout the world, eighteen different theories existed on the origin of ambergris, and various animals were considered producers of this substance—including seals, crocodiles, and birds. In modern times, scientists have finally figured out its origin.
Ambergris is an abnormal secretion in the digestive tract of the giant sperm whale. The sperm whale, Physeter macrocephalus, is the largest toothed whale in the world. I once saw a sperm whale skeleton specimen in a museum in Indonesia; the skeleton was nearly 20 meters long. Sperm whales are giant creatures in the sea, with big heads, big mouths and big appetites. They especially like to eat cuttlefish and squid, such as octopus and even the huge king squid in the deep sea.

Sperm whale preying on giant squid (Drawn by Duan Xu)
Although cuttlefish and squid have soft bodies, they have a hard plate inside their bodies, like an internal shell. The sperm whale swallows them whole. These hard organs enter the sperm whale’s stomach where they cannot be digested, but easily stimulate the sperm whale’s digestive secretions.
As time goes on, a dense oily or waxy secretion envelops the indigestible material, eventually forming a “block stone” that remains in the sperm whale’s body for a long time.
After the sperm whale dies, as the carcass decomposes, these “block stones” are discharged into the sea. Whale meat can rot, but lumpy stones cannot. Because of the rich wax, the “block stones” will drift with the current, floating on the sea for a long time. After years of continuous oxidation and transformation of nature, it finally becomes the precious ambergris. The longer it floats at sea, the better the quality, the fewer the impurities, and the lighter the color— old ambergris is almost white in color.
The First Time I Saw—and Touched– Ambergris
After working in Chinese medicine for more than 30 years, I finally saw authentic ambergris with my own eyes. Mr. Li Zhenxiong, an elderly specialist in precious Chinese medicinal materials, had ambergris as one of the treasures in his store.

Mr. Chun-hung Lee and I stand in his shop, holding one valuable piece of ambergris
There was a special smell when Mr. Li opened the cabinet storing ambergris. There are many adjectives for the aroma, such as delicate, strong, light, clear, and sweet. It is recorded in the literature that ambergris has a distinct fragrance. After smelling it myself, I finally knew that the distinct smell of ambergris is actually a fishy smell. Other people describe the fragrance as musky with hints of tobacco and the ocean. Indeed, ambergris is similar to musk. There is a principle in Taoist philosophy that says, “Yin at its extreme becomes Yang.” Or we may say, when things develop to their extreme, they become their opposite. So it is with ambergris. In large quantities, the smell is strong and unpleasant; only in very small quantities, as in perfume, does it seem fragrant and exotic.
Mr. Li put a large piece of ambergris in front of me. The shape of this piece of ambergris was irregular, grayish-white on the surface with dark brown appearing in the cross-section. It felt soft and light. If you looked closely, you could also see small, white traces of the indigestible cuttlefish bones, or broken bone residue, left inside. I put a small amount in my mouth; it tasted a bit sour and stuck to my teeth. Such a piece of ambergris, the size of two fists, is worth more than one million Hong Kong dollars.
Ambergris can be tested with fire, and the aroma emitted after being ignited is particularly charming. When ambergris is lit, it emits white smoke and is fragrant; if it is contaminated with amber, when ignited, it emits black smoke and has a resinous aroma.
Medical Functions of Ambergris
The major medicinal uses of ambergris are to resolve phlegm and relieve breathlessness, promote Qi and dissipate stagnation. Like other fragrant materials, it is mostly used in combination with other herbs in formulas, rather than alone.
Many ancient and modern medical books record ambergris; however, only a few formulas have been produced as proprietary medicines. In the National Prescription Collection of Traditional Chinese Medicine published in the 1950s, Lu Si Ke Wan were mentioned. This is a gold foil-coated honey pill that includes ambergris in the formula. It was mainly used for diseases such as whooping cough in children.
In ancient times, as with medicines, incense and perfumes were produced according to formulas, and these formulas typically had multiple ingredients. Very few were made of only one aromatic material.
Li Shizhen mentioned that using only ambergris as incense is not good, but using a little in combination with other ingredients can preserve their fragrance in incense. Li Shizhen wrote: “Ambergris can preserve the smell of borneol and musk for decades.” In other words, ambergris is a fixative, and nowadays, it is primarily used for that purpose.
One of the requirements for evaluating the grade of perfume is the longevity of the fragrance. Among the aromatic materials used in high-end perfumes on the market, the most precious fixative is still ambergris.

Nature’s Time-honored Gift
Like bezoar, ambergris is a pathological product. Sperm whales must suffer and die, and the massive stones from their intestines need to float at sea for dozens of years. Only then, do we get the rare, exotic, and precious ambergris.

龍涎香
——前世今生盡是謎
趙中振,博士,香港浸會大學
梁鸝,博士,香港浸會大學
關鍵字:龍涎香、定香劑、抹香鯨、太平惠民和劑局方、鷺鷥咳丸、墨魚
不可以貌取石
中國古代四大香,龍、檀、沉、麝,龍涎香位列第一。關於龍涎香,幾年前的一條新聞,引起了關注。2014年6月1日,兒童節,有位陳先生和家人一起到廈門的觀音山海濱去遊玩。他在海灘上看見了一塊拳頭大的“石頭”,他撿起來一模是軟的,一點也不重,看上去又有些像被海水浸泡過樹樁,但是臭烘烘的。陳先生走出去沒多遠,忍不住又轉回來了,再撿起來剛才那塊東西聞了聞,又丟在海灘上了。第三次,他已經走出去很遠了,但腦子裡突然冒出一個想法,這會不會是以前傳說中龍涎香呀。於是他急忙跑了回去。就這樣,一日三回頭,最後還是把這塊“臭石頭”帶了回來。他抱著一絲僥倖心理,去找專家經鑒定,得到結論這塊“石頭”果然是傳說中的龍涎香。經過化學分析後,其中龍涎香醇的含量高達25%,屬於龍涎香中的上品。


李震熊先生的私家龍涎香臻藏;龍涎香色澤多變,自深黑至近乎純白皆有
這條新聞播出後,那片海灘一下成了尋寶聖地。原本海邊遊玩的人,也不撿貝殼了,注意力轉到黑黢黢的石頭上。可是貝殼容易尋,龍涎香實難遇見。撿到龍涎香雖說是真事,但大概和中彩票的幾率差不多吧。
灰色琥珀之謎
古時候不但中國人搞不清龍涎香的來源,外國人也搞不清。龍涎香是個外來香藥,最初在阿拉伯海及非洲海岸被發現。
阿拉伯語中龍涎香的音為Ambar,所以在中國古代將其音譯為俺八兒香或阿末香。龍涎香的英文名字Ambergris,翻譯成中文的意思就是灰色的琥珀。
由於龍涎香來自海上,古人把它和龍掛上了鉤。龍是想像中的動物,這就給龍涎香更增添了一層神秘的色彩,多了一分尊貴。
龍涎香被收錄於《本草綱目》鱗部第四十三卷。李時珍記載龍涎香,出西南海洋中。關於龍涎香是何物,李時珍也搞不清楚,記載它是龍的涎沫,又說可能是大魚腹中產物。究竟是哪一種,李時珍沒有能下定論,仍是推測。
到了現代,現代科學家終於理清了它的基原。
龍涎香是抹香鯨消化道中的異常分泌物。抹香鯨Physeter macrocephalus是世界上最大的齒鯨。我在印尼的一家博物館內,曾見過抹香鯨骨架標本,有將近二十米長。抹香鯨是海中的龐然大物,頭大、嘴大、胃口大,特別喜歡吃烏賊、章魚、魷魚等軟體動物,包括深海裡體型巨大的大王烏賊。

抹香鯨捕食大魷魚(段煦繪製)
軟體動物雖然身體柔軟,但它們體內有特別堅硬的角質齶。進食過程中,這硬質的器官如同一把利刃進入了抹香鯨的腸胃,不但不會被消化,還容易刺激抹香鯨的消化道。
出於生物的自我保護機制,抹香鯨的腸道內會分泌出粘稠而質密的油狀或蠟狀的分泌物,將不消化的物體包裹住形成一種“塊狀結石”,長期留在抹香鯨的體內。
等到抹香鯨死亡之後,隨著屍體的腐爛,這些“塊狀結石”被排放到大海之中。鯨魚肉能夠爛掉,但塊狀結石爛不了。由於富含蠟質的緣故,“塊狀結石”會隨波逐流,如同“漂流瓶”一樣,長期漂在海面上。經過大自然長期持續的氧化與轉化,最終成為珍貴的龍涎香。不一定每只抹香鯨體內都能產生龍涎香。一塊龍涎香需在海上浮沉幾十年、甚至上百年,經過歲月的洗禮。一般來說,在海上漂浮的時間越久的龍涎香,品質越好,雜質越少,顏色越淺,接近白色。
我見龍涎香
我自己也是在從事中藥工作30多年後,才在香港一個中藥老前輩——李震熊先生的店鋪裡,才見到龍涎香的真容。李老先生是專門經營名貴中藥材的行業前輩,龍涎香是他店中珍藏之一。

Mr. Chun-hung Lee and I stand in his shop, holding one valuable piece of ambergris
李震熊先生與我,在他的店裡,手中托著一塊價值不菲的龍涎香
當李老先生打開存放龍涎香的櫃子時,我聞到一種特殊的氣味。中國人對於香氣的形容詞特別多,幽香、濃香、淡香、清香、甘香,還有異香。以往文獻記載龍涎香就是異香。什麼是“異香”,聞過龍涎香以後我才知道。所謂的異香就是一種腥臭。物極必反,龍涎香和麝香都是這樣,香過頭了,反而不覺得是香的。
李老先生把一大塊龍涎香擺在我的面前。 只見這塊龍涎香形狀不太規則,外表偏灰白色,斷面有些偏黑褐色的物質,手感較軟,質地也比較輕。仔細觀察還能看見裡面殘留著的、消化不了的、白色小塊墨魚骨,或破碎的骨頭渣的痕跡。我取了一小點嘗了嘗,味道有些酸澀,粘牙。這樣一塊兩個拳頭大小的龍涎香,價值已超過百萬港幣。
龍涎香可以用火試,點燃後散發出的香氣,特別迷人。龍涎香點燃後冒白煙,有香氣;如果用琥珀來冒充的話,點燃後冒出的是黑煙且為松香味。
龍涎香的妙用
龍涎香主要功效為化痰平喘,行氣散結,利水通淋。
雖有不少古今的醫藥著作記載了龍涎香,但落實到具體藥物的記載卻不算多。20世紀50年代出版的《全國中藥成藥處方集》當中保留了鷺鷥咳丸。這是一種金箔包衣的蜜丸,組方中就用到了龍涎香,主要用於小兒百日咳等疾病。
其實,古代的香由單一香藥製成的“單品香”很少,主要還是以“合香”為主,古人制香有香方,如同中藥有複方一樣。
李時珍記載單用龍涎香來熏,氣味不佳。但它能聚香,有合群之妙。需要用到合香的藥物,就像中藥處方裡常用甘草調和諸藥一樣。李時珍寫到:“龍涎,能收腦(龍腦香)、麝(麝香)數十年不散。”龍涎香的作用,可用來收香,就是現在所說的定香劑的作用。
現在評價香水的等級的其中一條要求就是留香時間。市售的高級香水所用的香料裡,最珍貴的定香劑依然是龍涎香。龍涎香可令香氣更富有層次,並讓香的效果發揮到極致。

自然之饋,歷久彌珍
龍涎香與牛黃、猴棗一樣,是一種病理產物。最難得的是,抹香鯨體內的這種塊狀結石需要海上漂浮至少數十載,經過時間的打磨,才能變成真正的龍涎香。

